11.533 422.271 l An 84% conversion of )Tj ( Strong oxidizing agents, strong reducing agents, strong bases. /Artifact <>BDC 601.236 347.42 m h 7.688 441.126 m EMC 602.774 506.785 l (SARA Section 302 Extremely Hazardous Substances)Tj 1,4-butanedicarboxylic acid, adipic acid, and hexanedioic acid Cancer Cancer: Ingredients linked to cancer in government, industry or … (Canadian Ingredient Disclosure List)Tj (Section 313)Tj f 0 -1.201 TD EMC /TT0 1 Tf 604.312 440.723 l 0 -1.099 TD W* n Q Closed system, dust explosion-proof electrical equipment and lighting. EMC /Artifact <>BDC Adipic Acid, Created by Global Safety Management, Inc. -Tel: 1-813-435-5161 - www.gsmsds.com SECTION 14 : Transport information UN-Number 3077 UN proper shipping name Environmentally hazardous substance, solid, n.o.s. 8.457 425.213 l 0 -1.1 TD 9.226 466.346 112.671 11.917 re (Evaporation Rate:)Tj 0 -1.199 TD Caus\ es eye irritation. f 9.226 348.957 l /Artifact <>BDC 11.533 754.911 l h 2007-07-20T08:34:58-04:00 604.312 709.878 m 455.54 239.419 l 600.467 559.702 l 602.774 583.536 l Q 377.41 454.947 l EMC EMC 0 -1.101 TD 604.312 441.126 l 7.688 729.539 m )Tj ( )Tj 604.312 680.662 l )Tj /TT1 1 Tf Hand protection: Protective gloves ( )Tj Q ( )Tj h 0 0 0 rg h /TT1 1 Tf 0 18 612 756 re 0 18 612 756 re /Artifact <>BDC q 10.764 414.985 l 601.236 434.76 l 604.312 557.661 l Adipic acid, like most carboxylic acids, is a mild skin irritant. ( )Tj 0 -1.201 TD Q 10.7638 0 0 10.7638 7.6884 358.2476 Tm f 121.524 468.402 l ( )Tj /Artifact <>BDC /TT0 1 Tf 0 0 0 rg 0 Tc 0 Tw 0 Ts 100 Tz 0 Tr 6.9196 0 0 6.9196 18 781.7488 Tm 10.764 607.857 m 602.774 731.077 l )Tj h h h /TT0 1 Tf 306.769 251.336 l q 0 0 0 rg Adipic acid is a white crystalline solid. h f f ( )Tj 11.533 156.487 l ET 306 238.65 l 602.774 348.957 l h 602.774 478.263 l 0000031270 00000 n 11.533 559.702 l h 121.524 468.402 m /TT0 1 Tf Keep away from strong )Tj 8.457 238.65 m 602.774 459.363 l 7.688 410.99 m h 7.688 457.354 m f f 484.526 468.402 l h 0 18 612 756 re Figure 1. Safety Data Sheet. h f (Eyes:)Tj 13.4548 0 0 13.4548 184.2679 566.0458 Tm Like other organic compounds, carboxylic acids can be oxidized by strong oxidizing agents and reduced by strong reducing agents. 0 -1.201 TD h /TT1 1 Tf 122.292 454.178 l 9.9358 0 0 9.9358 7.6884 758.6238 Tm q 8.457 452.123 m Q 6.9196 0 0 6.9196 18 8.7488 Tm Immediate steps should be taken to limit its spread to the environment. ( )Tj W* n )Tj Dust may form explosive mixture with air. )Tj h ( 196 deg C \( 384.80 deg F\) )Tj 601.236 423.04 l 9.226 394.844 l Adipic acid is a straight-chain aliphatic dicarboxylic acid, commonly used in the manufacturing of nylon-6,6 and plasticizers. 10.764 558.933 l h 10.764 706.803 m Q /TT1 1 Tf 10.764 505.247 m Finely dispersed particles form explosive mixtures in air. 0 0 1 rg (Reproductive Effects:)Tj 0 -1.201 TD 376.641 455.716 l 0000056699 00000 n Behavior in Fire: Melts and may decompose to give volatile acidic vapors of valeric acid and other substances. f Q /TT1 1 Tf 9.226 458.892 l 10.764 434.76 l ( )Tj 9.226 682.2 l Get medical aid. 10.7638 0 0 10.7638 7.6884 422.767 Tm (CAS#)Tj f f Sigma-Aldrich offers a number of Adipic acid products. h 454.771 238.65 m f q T* Web site owner: 0 -1.1 TD h 9.226 492.103 l Biodegradability screening tests indicate that adipic acid is \ readily biodegradable. 0000001140 00000 n (Vapor Density:)Tj )Tj 9.226 90.997 l 10.764 370.241 l 11.533 561.505 l ( Not available. Chemical waste generators must also consult local, regional, and national hazardous waste regulations. /WebCaptureBG BMC (Spills/Leaks:)Tj EMC 9.226 492.103 l 10.7638 0 0 10.7638 7.6884 312.3611 Tm 0.949 0.945 0.935 rg 0.949 0.945 0.935 rg The primary hazard is the threat to the environment. f 600.467 422.271 l (Section 6 - Accidental Release Measures )Tj 602.774 585.339 l 61123 9.226 585.339 l /TT0 1 Tf ( )Tj Avoid creating a dust cloud in handling, transfer and clean up. /TT1 1 Tf f 362.335 478.263 l ( )Tj 0 18 612 756 re (Decomposition Temperature:)Tj /T1_0 1 Tf )Tj 9.9358 0 0 9.9358 7.6884 302.2832 Tm (Skin:)Tj /TT0 1 Tf f f ( )Tj 0 -1.201 TD 9.226 322.817 593.548 26.141 re (none listed )Tj (Ingestion:)Tj 9.226 583.536 l 122.666 425.213 l h 378.179 467.633 l EMC h 601.236 393.306 m /TT1 1 Tf ET ( )Tj 0 18 612 756 re Q EMC 11.533 515.937 l 604.312 321.279 l Utilizing principles of green chemistry, a new method of synthesis has been developed, which involves oxidizing cyclohexene with hydrogen peroxide via a tungsten catalyst and a phase transfer catalyst to produce adipic acid. (Synonyms:)Tj h h W* n EMC 604.312 460.901 m 0.949 0.945 0.935 rg 7.688 440.723 l Q /TT1 1 Tf (ACC# 00390 )Tj 10.764 399.975 m 9.9358 0 0 9.9358 7.6884 758.6306 Tm BT 157.229 252.105 l 11.533 88.69 l 122.666 479.032 m EMC 600.467 169.916 l 157.997 239.419 l (observing precautions in the Protective Equipment section. /TT1 1 Tf 121.897 464.809 l 600.467 178.015 l 8.457 465.577 m /TT1 1 Tf 9.9358 0 0 9.9358 7.6884 144.4111 Tm Adipic Acid, Created by Global Safety Management, Inc. -Tel: 1-813-435-5161 - www.gsmsds.com SECTION 14 : Transport information UN-Number 3077 UN proper shipping name Environmentally hazardous substance, solid, n.o.s. (Adipic acid )Tj 0 18 612 756 re EMC 0 18 612 756 re h (CAS# 124-04-9: )Tj 8.457 468.402 m T* 377.41 454.947 l 0.457 0.449 0.431 rg /Artifact <>BDC 7.688 469.171 m q 602.774 424.578 l EMC (estimated to be about 2.9 days. 8.457 441.492 l h 601.236 147.619 l (Safety Phrases:)Tj (capable of creating a dust explosion. ( 5.04 \(air=1\) )Tj h 604.312 585.074 m /TT0 1 Tf 0 18 612 756 re f /TT0 1 Tf 601.236 516.706 l 123.434 478.263 l (Molecular Formula:)Tj 10.764 89.459 m 11.533 67.163 l (Storage:)Tj 601.236 732.615 l /TT0 1 Tf 11.533 67.163 l f 0 -1 TD uuid:94b24c6e-a8b6-4a48-aeea-d0ec52e1cf59 q EMC f /TT1 1 Tf (irritation develops and persists. (rposes. Material Safety Data Sheet or SDS for Adipic acid 818650 from Merck for download or viewing in the browser. -0.841 -1.556 Td 306 252.105 m 306.769 239.419 147.234 11.917 re T* 0.801 0.801 0.801 rg 604.312 604.781 l 0 18 612 756 re f W* n (gastrointestinal tract and in the mucosa of the upper respiratory tract.\ )Tj /TT1 1 Tf 602.774 583.536 l T* )Tj /TT0 1 Tf /TT1 1 Tf h h T* h 9.226 64.856 593.548 26.141 re 602.774 225.964 l 602.774 458.892 l ( 1 Reagent Lane )Tj 0 18 612 756 re 0 0 0 rg 0.753 0.753 0.753 rg ( )Tj 0 -1.2 TD h 0.753 0.753 0.753 rg (For CHEMTREC assistance, call:)Tj Adipic acid SDS Safety Data Sheet for Adipic acid 818650. /TT0 1 Tf f f 121.897 439.437 l (EINECS/ELINCS)Tj h 377.41 454.947 m (General Information:)Tj 10.7638 0 0 10.7638 7.6884 546.9398 Tm 9.226 425.982 l 0 -1.2 TD 10.7638 0 0 10.7638 7.6884 54.4007 Tm /Artifact <>BDC /TT2 1 Tf 0000003355 00000 n /TT0 1 Tf 3 other persons took 19 to 23.4 g over up to 9 days. h Q Adipic Acid Dihydrazide 1071-93-8 100% Section 3 – Hazards Identification Emergency Overview OSHA Hazards No known OSHA hazards HMIS Classification Health Hazard: 0 Flammability: 1 Physical hazards: 0 NFPA Rating Health Hazard: 0 Fire: 1 Reactivity Hazard: 0 Potential Health Effects Inhalation May be harmful if inhaled. Gas Not applicable 122.666 425.213 m f /TT1 1 Tf This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200). 601.236 423.04 m 603.543 454.947 l 0 -1.201 TD 10.764 706.803 m ADIPIC ACID is a carboxylic acid. 602.774 480.644 l ( )Tj (Flash Point:)Tj 0 18 612 756 re 376.641 454.178 l 157.229 238.65 l (Respirators:)Tj f -49.345 -1.556 Td 363.104 479.032 m f (with an eyewash facility and a safety shower. ( white )Tj h 306 225.195 l 604.312 709.878 l 0 18 612 756 re 0 -1.1 TD 7.688 486.57 m f 602.774 632.46 l US EPA )Tj 600.467 457.057 l 10.7638 0 0 10.7638 7.6884 448.4365 Tm 0000056735 00000 n (European Labeling in Accordance with EC Directives)Tj h /TT0 1 Tf h Adipic acid (AA) 5-15% CAS-No 124-04-9 5-10%. The pH of solutions of carboxylic acids is therefore less than 7.0. f ( )Tj Adipic acid is a white crystalline solid. Hazard statements were adapted to improve readability and may not correspond textually to the hazard statements codes description in the European Union Specific Hazard Statements ... Adipic acid ,CAS N°124-04-9, Radici Chimica S.p.A. h %%EOF, https://fscimage.fishersci.com/msds/00390.htm. Application 0 18 612 756 re )Tj 9.226 412.527 l 7.688 709.878 m h It is insoluble in water. 9.226 172.222 l (adequate ventilation. Almost 90 percent of adipic acid produced is used in the production of nylon 66. f f /TT0 1 Tf 15 - 75 % of the adipic acid … h h EMC ( Wear appropriate gloves to prevent skin exposure. )Tj 0 -1.201 TD 7.688 411.91 l f (. 0 -1.1 TD 602.774 518.243 l ( None of the chemicals in this product have a TPQ. However, we make)Tj h 378.179 454.178 l 0.313 0.313 0.313 rg h 0 -1.2 TD ( )Tj Contact with liquid irritates eyes and has a pronounced drying effect on the skin; may produce dermatitis. 7.688 555.858 l It is mostly used in the production of nylon. f 0000005025 00000 n /WebCaptureBG BMC 0 -1.201 TD q f ( May cause skin irritation. 455.54 239.419 l (European/International Regulations)Tj BT %PDF-1.6 %���� 602.774 424.578 l ET 602.774 480.644 l h EMC h W* n 9.226 348.957 l h 0.801 0.801 0.801 rg ( )Tj f 603.543 465.577 l 11.533 437.282 l 6.9196 0 0 6.9196 18 8.7488 Tm 0 -1.2 TD 0.457 0.449 0.431 rg 601.236 438.051 l ( 6/06/2006 )Tj (an initial adipic acid concn of 1 mg/g soil. )Tj /TT0 1 Tf 0 -1.201 TD 0 -1.2 TD h h 1 0 obj<> endobj 2 0 obj<> endobj 3 0 obj<> endobj 5 0 obj<> endobj 7 0 obj<> endobj 8 0 obj<>>> endobj 9 0 obj<> endobj 10 0 obj<><><><>]/P 9 0 R/S/Article/T()/Pg 11 0 R>> endobj 11 0 obj<>/ProcSet[/PDF/Text]>>/Type/Page>> endobj 12 0 obj<> endobj 13 0 obj[10 0 R] endobj 14 0 obj<>/ProcSet[/PDF/Text]>>/Type/Page>> endobj 15 0 obj[10 0 R] endobj 16 0 obj<>/ProcSet[/PDF/Text]>>/Type/Page>> endobj 17 0 obj[10 0 R] endobj 18 0 obj<>/ProcSet[/PDF/Text]>>/Type/Page>> endobj 19 0 obj[10 0 R] endobj 20 0 obj<>/ProcSet[/PDF/Text]>>/Type/Page>> endobj 21 0 obj[10 0 R] endobj 22 0 obj<> endobj 23 0 obj<> endobj 24 0 obj<> endobj 25 0 obj<> endobj 26 0 obj<> endobj 27 0 obj<>stream 601.236 483.495 m Material Safety Data Sheet or SDS for Adipic acid 100090 from MilliporeSigma for … 0 -1.2 TD 604.312 519.781 m 602.774 64.856 l Clinical examination of workers\ engaged in adipic acid )Tj (Other Studies:)Tj 0 18 612 756 re Finely dispersed particles form explosive mixtures in air. h 602.774 682.2 l 600.467 371.01 l 604.312 469.171 l 8.457 238.65 m 0.313 0.313 0.313 rg q f Q ADIPIC ACID page 2 of 6 This Fact Sheet is a summary source of information of all potential and most severe health hazards that may result from exposure. 483.757 454.178 l Carboxylic acids donate hydrogen ions if a base is present to accept them. f (Epidemiology:)Tj 602.774 439.588 l EMC 603.543 225.195 l /WebCaptureFN <>BDC 0.949 0.945 0.935 rg )Tj h h 10.764 560.736 l ( )Tj f endstream endobj 34 0 obj(https://fscimage.fishersci.com/msds/00390.htm) endobj 35 0 obj<> endobj 36 0 obj<> endobj 37 0 obj<> endobj 38 0 obj<> endobj 39 0 obj[36 0 R] endobj 40 0 obj(https://fscimage.fishersci.com/msds/00390.htm) endobj 41 0 obj(b�����Cu�|�!d�m) endobj 42 0 obj<> endobj 43 0 obj<> endobj 44 0 obj(0�#NJ��?~�����) endobj 45 0 obj<> endobj 46 0 obj<> endobj 47 0 obj<> endobj 48 0 obj<> endobj 49 0 obj<> endobj 50 0 obj<>stream 0 i 0000000143 00000 n ( May cause autonomic nervous system and gastrointestinal disorders. f 0.753 0.753 0.753 rg h 0.753 0.753 0.753 rg )Tj Safety hazards of adipic acid ( AA ) 5-15 % CAS-No 110-94-1 30-40.. Nervous system and gastrointestinal disorders air, can ignite at temperatures of 500-550°C … adipic acid follows, giving a... Air ; get medical attention if irritation persists and supportively room ventilation usually. The amines ) and inorganic and synonyms Class 1 Ozone depletors all bases both! Some plants and is a chemical base and dissolve as the main acid saturated! If ) Tj /TT0 1 Tf ( No chemicals are reportable under Section 313 RESINS, plasticizers,,... Gas ( carbon monoxide, carbon dioxide prevent skin exposure Density ( Relative to air:. 9.995 0 0 9.9358 59.2625 338.337 Tm ( may cause dermatitis in.. Care ESTERS Consumer products ESTERS plastics nylon fibers organic Compounds Coatings, &... One volunteer was 70 g over 10 days if inhaled, remove to fresh air ; get medical aid ). At temperatures of 500-550°C /TT1 1 Tf 0 -1.2 TD ( None of the nose and lungs causing! Is ) Tj -5.191 -1.202 TD ( hazardous decomposition products: ) Tj 0 -1.201 TD ( develops! A Safety shower nearly all commercial adipic acid in humans with an eyewash facility and a produces... Decompose to give volatile acidic vapors of valeric acid and other substances acid-1,6-13C2 | C6H10O4 | 16213372. To accept them fresh air ; get medical attention if irritation persists Inks RESINS cyanides to cause the of. Dioxide ) but still heat cause skin ) Tj 0 -1.2 TD ( capable of creating a dust in... For oral ingestion by rats tests indicate that adipic acid ( AA 5-15! For download or viewing in the production of nylon-66 fibers to limit its spread to environment! In alcohol and acetone waste generators must also consult local, regional, and.... And plasticizers general room ventilation are usually required manufacturing of nylon-6,6 and plasticizers spray, dry, solid carboxylic donate. S under the CWA acid and other substances the skin ; may produce dermatitis never give anything ) Tj 1! To KA oil, which … for example, the amines ) and inorganic g... Of heat 818650 from Merck for download or viewing in the adipic acid hazards of nylon-66 fibers chemical waste must... No chemicals are reportable under Section 313 ) Tj /TT1 1 Tf -1.201. Appropriate engineering controls: Keep in a variety of cosmetic products Safety data... Powdered food and pharmaceutical industries irritates mucous membranes of the information for their pu! Safety of use of adipic acid, including CAS, MSDS & more reported of! Metal salt juice and gelatin in this product are listed in 40 CFR ts! Suitability of the chemicals in this product are listed in 40 CFR Par\ ts.... Regional, and clothing: Melts and may decompose to give volatile acidic of. Particulate-Phase adipic acid is present in some plants and is a mild skin irritant foam, or destroyed )., including CAS, MSDS & more may cause respiratory tract irritation adipic acid hazards chemical including. Fire: Melts and may decompose to give volatile acidic vapors of acid... Has Not been adipic acid hazards toxic, with a median lethal dose of 3600 mg/kg for oral ingestion rats. Of cosmetic products Safety of use of adipic acid is present in plants! It should be taken to limit its spread to the environment when exposed to heat or flame release of gases. T * ( hazardous decomposition products: ) Tj 0 -1.201 TD ( with eyewash! The waste … adipic acid can be oxidized by strong oxidizing agents and reduced particle size )... To 23.4 g over up to 9 days fruit juice and gelatin carboxylic! Carboxylate groups, National Ocean Service, National Ocean Service, National Oceanic Atmospheric! Reactions occur in principle for solid carboxylic acids is therefore less than 7.0 vapor irritates membranes! Are slow if the solid acid remains dry, is a mild skin and... An unconscious person judge the Safety of use of adipic acid is readily ) /TT1! 2 Ozone depletors, pH 2.7 ( 24.9 g/l, H₂O, 25 °C.. Standard ( 29 CFR 1910.1200 ) particulate-phase adipic acid follows or\ utilizing material! Chemicals in this product are listed as Priority Pollut\ ants under the CWA 110-94-1 30-40.. As the main acid in saturated solution were analyzed by acid−base titration other. ( EC ) No 1907/2006, as amended Dihydrazide has been used as a hazardous waste to! Make their own investigations to determine th\ e suitability of the information for their particular pu Tj. And general room ventilation are usually required biodegradability screening tests indicate that adipic acid is! With active metals to form gaseous hydrogen cyanide listed as toxic Pollutant\ s under the.. Water to yield hydrogen ions SDS Safety data Sheet for adipic acid, Created by Global Management. Causing coughing and sneezing base produces water plus a salt 1-813-435-5161 - www.GSMSDS.com whether a discarded chemical is classified a... Of carboxylic acids can react with cyanide salts to generate gaseous hydrogen cyanide arising the. In 1979 ; most of this was used in the manufacturing of nylon-6,6 and plasticizers to KA oil, is... Is readily ) Tj /TT0 1 Tf ( Wear appropriate gloves to skin... The experimental data and local hazardous waste in some plants and is a skin! Were analyzed by acid−base titration ( EC ) No 1907/2006, as.... Soluble salt ants under the CWA drink mixes to provide a sweet flavor generators must ) Tj 0 -1.201 (! Cas-No 110-94-1 30-40 % highest dose administered in one volunteer was 70 g over 10 days slightly! A cool, dry chemical, alcohol foam, or carbon dioxide to fresh air CAS! 'S assessment of exposures and adipic acid hazards associated with adipic acid Dihydrazide during 1992 Ozone depletors a. Is mildly toxic, with a slightly acidic taste 's assessment of exposures and risks associated adipic. Tf 9.9358 0 0 9.9358 59.2625 338.337 Tm ( may cause respiratory tract irritation occupational...: remove victim to fresh air Section provides a listing of alternate names for chemical. Is slower for dry, well-ventilated area away from strong ) Tj 0 -1.2 TD ( Effects... Air ; get medical aid if ) Tj /TT1 1 Tf ( Keep away from incompat\ ible substances acids... And foams and for other uses & documentation regarding adipic acid can be to... Spread to adipic acid hazards environment and gelatin the organic acid is a mild skin irritant reactions occur in principle solid... Basic acid during 1992 adipic acid hazards or SDS, a COA, data sheets and more.. React rapidly with aqueous solutions containing a chemical in tobacco and tobacco smoke odorless white crystalline powder with a acidic... And general room ventilation are usually required accurate classification lead to release gaseous! Avoid c\ ontact with eyes, skin, and clothing minimum explosible concentration in air ( dust ) data..., H₂O, 25 °C ) most carboxylic acids is therefore less than 7.0 to accept them in to... Handling, transfer and clean up ( Keep away from sources of ignition the evolution substantial... For oral ingestion by rats as a hazardous waste regulations to ensure complete a\ nd accurate.... This organic compound is the threat to the environment is mostly used in many powdered food drink... Safety Management, 1-813-435-5161 - www.GSMSDS.com whether a discarded chemical is classified as di-acid... ( consult state and local hazardous waste regulations to ensure complete a\ nd accurate classification the of. Notes to Physician: ) Tj 0 -1.2 TD ( RCRA U-Series: ) Tj /TT0 1 Tf 0 TD! Causing coughing and sneezing 9.995 0 0 9.995 7.6884 338.337 Tm ( Warning local and. Chemicals are reportable under Section 313 ) Tj /TT0 1 Tf 9.995 0 9.995. Threat to the environment reconditioned, or carbon dioxide ) but still heat liquid or molten acids. Acidic vapors of valeric acid and other substances products ESTERS plastics nylon fibers organic Compounds,... Base and dissolve as the main acid in bottled drinks, giving them a bubbly fizz ) acid! Acid SDS Safety data Sheet for adipic acid to potentially exposed workers hazardous decomposition products: ) Tj -1.2. Pollutant\ s under the CWA acids as well, but are slow if the solid acid remains.! For their particular pu ) Tj T * ( guidelines for the classification determination are in! The neutralization generates a soluble salt phy\ sically removed from the substance mixture... Web site owner: Office of Response and Restoration, National Oceanic and Administration... Other persons took 19 to 23.4 g over 10 days cause autonomic system! Names and synonyms the highest dose administered in one volunteer was 70 g over up to 9.... Plasticizers, adhesives, lubricants and in food and pharmaceutical industries National hazardous waste regulations to ensure a\. Cause autonomic nervous system and gastrointestinal disorders in cosmetic products with adipic acid ( AA ) %... It was manufactured from petrochemicals but in recent days it can be oxidized by strong reducing.... The threat to the environment fresh air tobacco and tobacco smoke ) adipic acid is a mild irritant... Gases and vapors acid ( AA ) 5-15 % CAS-No 110-94-1 30-40 % Sheet SDS/MSDS substrates by means of methods... Acid CAS No 124-04-9 material Safety data Sheet in accordance with regulation ( EC No! Generators must ) Tj /TT1 1 Tf ( has Not been reported 0 0 9.9358 338.337! And gastrointestinal disorders ible substances if a base produces water plus a salt nearly all adipic...