55,823. Phthalic acid is one of three isomers of benzenedicarboxylic acid, the others being isophthalic acid and terephthalic acid. Ea'ample I A sample of the meta.-phtha'l ate of di-valent ,leacl having a White color' was placed in an Example II A second sample of" the meta-phthalate of divalent lead was placed in an enclosed glass reaction vessel in an oxidizing atmosphere (air) and heated to a temperature of between degrees Fahrenheit and 850 degrees Fahrenheit for 10 minutes. Temperatures between 500 degrees Fahrenheit and "850 degrees Fahrenheit have been found suitable for the preparation of meta-phthalic anhydride by heating of a salt of a di-valent metal andmeta-phthalic acid. 8. PubChem Substance ID 329763040. Typically phthalate esters are prepared from the widely available phthalic anhydride. 3. This meta-analysis aims to evaluate the association between five different phthalate metabolites and endometriosis, based on current evidence. The isophthalic acid market was rather tight during 2017 and part of 2018, but there have been new investments in 2019. Phthalamic acid definition is - a crystalline compound HOOCC6H4CONH2 formed by reaction of phthalic anhydride and ammonia; the half amide of phthalic acid. Phthalic acid, also called benzene d-carboxylic acid, has the chemical formula C 6 H 4 (COOH) 2. Molecular Weight 245.03 . The material is slightly soluble in hot water to give a solution having an acid reaction. and condensing the meta-phthalic acid anhydride. Having described my invention, what I claim as novel and desire to secure by Letters Patent is: l. A process for preparing the inner anhydride of meta-phthalic acid which comprises heating the inner salt of meta-phthalic acid and a divalent metal to'a'temperature of 500 degrees F. to approximately 850 degrees F. to form metaphthalic acid anhydride vapor and then condensing the meta-phthalic acid anhydride vapor. Isophthalate. '7. Slender transparent to white needles and feathers of meta-phthalic anhydride sublimed and condensed in cooler parts f the reaction vessel. phthalic acid (plural phthalic acids) (organic chemistry) Any of three isomeric aromatic organic benzenedicarboxylic acids, C 6 H 4 (COOH) 2; especially the ortho-isomer manufactured from naphthalene, used in the synthesis of dyes, perfumes and other compounds. The (1,3-benzenecarboxylic acid) is the meta form of phthalic acid. Synonym: 1,2-Benzenedicarboxylic acid 1,2-bis(1-methylethyl) ester, NSC 15315, Phthalic acid diisopropyl ester Empirical Formula (Hill Notation): C 14 H 18 O 4 Molecular Weight: 250.29 How do you say Meta-phthalic acid? Phthalocyanines. Epub 2017 Jul 7. t. The same product is obtained when thesalt is heated alone .to slightly higher optimum temperatures. CHEBI:30802. [10], This article uses material from the Wikipedia article The toxicity of phthalic acid is low with LD50 (mouse) of 550 mg/kg. Environ Sci Pollut Res Int. Phthalic acid is a benzenedicarboxylic acid cosisting of two carboxy groups at ortho positions. The stoichiometry of the complex formation of TBP or TRPO and phthalic acid is 1:1, and the apparent extraction equilibrium constant for TRPO is much larger than that for TBP. However, many phthalate esters have been implicated as endocrine disruptors. THE INNER ANHYDRIDE OF METAPHTHALIC ACID. P1 degrades phthalic acid. Orthophthalic acid definition, See under phthalic acid (def. It is a white crystalline solid subliming at 345°C. 1‐octanol shows a good extractive selectivity for [1,1′‐biphenyl]‐2,2′‐dicarboxylic acid as compared with phthalic … iso-phthalic acid. V. Phenyl derivatives, Water-participation in the crystalline-state photodimerization of cinnamic acid derivatives. The irradiation may be in the presence of an oxidizing atmosphere, an inert atmosphere, or a vacuum, but should not be carried out in a reducing atmosphere. The material dissolves in aqueous alkali, such as ten percent sodium hydroxide solution; and when the sodium hydroxide solution is neutralized and rendered weakly acid with acetic acid, it gives an orange-pink color upon addition of ferric ion. 75701-44-9. meta phthalic acid anhydride acid anhydride degrees fahrenheit Prior art date 1948-10-15 Legal status (The legal status is an assumption and is not a legal conclusion. Example III Example IV A sample of anhydrous calcium meta-phthalate was placed in an enclosed glass reaction vessel in an oxidizing atmosphere (air) and heated to a temperature of approximately 800 degrees- Fahrenheit for minutes. 1). 2019 Apr;26(10):9435-9442. doi: 10.1007/s11356-019-04373-1. Poly(ester-b-carbonate)s are successfully synthesized for the first time through the metal-free copolymerization of cyclohexene oxide (CHO), propylene oxide (PO), phthalic anhydride (PA), and CO2 in a one-pot/one-step protocol. Empirical Formula (Hill Notation) C 8 H 5 BrO 4. 5-Bromoisophthalic acid Synonym: 5-Bromo-1,3-benzenedicarbonic acid, 5-Bromo-1,3-benzenedicarboxylic acid, 5-Bromoisophthalic acid CAS Number 23351-91-9. [5], Phthalic acid is produced by the catalytic oxidation of naphthalene or ortho-xylene directly to phthalic anhydride and a subsequent hydrolysis of the anhydride.[5]. See more. Creative Commons Attribution-Share-Alike License 3.0. NACRES NA.22 31, pp. m-Phthalic acid. [8] Manufacturing methods in the nineteenth century included oxidation of naphthalene tetrachloride with nitric acid, or, better, oxidation of the hydrocarbon with fuming sulfuric acid, using mercury or mercury(II) sulfate as a catalyst. The bacteria Pseudomonas sp. Phthalic acid was first obtained by French chemist Auguste Laurent in 1836 by oxidizing naphthalene tetrachloride. A process for preparing the inner anhydride of meta-phthalic acid which comprises heating the inner salt of meta-phthalic acid and a divalent metal selected from the group consisting of lead, copper, and calcium to a temperature of 500 degrees F. to about 850 degrees F. to form meta-phthalic acid anhydride vapor and condensing the meta-phthalic acid anhydride vapor. In each of Examples II to IV, the salt of a di-valent metal and meta-phthalic acid is heated for a sufiicient time and to a temperature to cause formation of meta-phthalic acid anhydride vapor which is separated from residual material as a vapor and then condensed. A process for preparing the inner anhydride of meta-phthalic acid which comprises heating the inner cupric meta-phthalate to a temperature of 500 degrees Fahrenheit to 850,degrees Fahrenheit to form meta-phthalic acid anhydride vapor. Substance identity Substance identity. It is slightly soluble in water, alcohol and acetic acid (insoluble in benzene). 6. Thank you for helping build the largest language community on the internet. PHTHALIC ACIDS, the name given to the three isomeric benzene-dicarboxylic acids, C6114(CO2H)2: (I) ortho, or phthalic acid; (2) meta, or isophthalic acid; (3) para, or terephthalic acid. The following examples illustrate the .in- Vention more specifically, but the invention is not intended to be limited by the examples except as set out in the appended claims. The reaction between indole and acetic anhydride, Process for the preparation of benzoic acid and benzoates, Bicyclic structures prohibiting the walden inversion. 8. Application Qetober 15, 1948, Serial No. A process for preparing the inner anhydride of meta-phtnalic acid which comprises heating the inner salt of meta-phthalic acid and a divalent metal to a temperature of approximately 750 degrees Fahrenheit to 850 degrees Fahrenheit to form meta-phthalic acid anhydride vapor, and condensing the meta-phthalic acid anhydride. A PROCESS FOR PREPARING THE INNER ANHYDRIDE OF META-PHTHALIC ACID WHICH COMPRISES HEATING THE INNER SALT OF META-PHTHALIC ACID AND A DIVALENT METAL TO A TEMPERATURE OF 500 DEGREES F. TO APPROXIMATELY 850 DEGREES F. TO FORM METAPHTHALIC ACID ANHYDRIDE VAPOR AND THEN CONDENSING THE META-PHTHALIC ACID ANHYDRIDE VAPOR. Patented Oct. 9, 1 951 OFF-EC META PHT-H-ALIC ACID ANHYDRIDE AND METHOD OF MAKING SAME GeorgeWalton, Cincinnati, Ohio N Drawing. Phthalic acid is an aromatic dicarboxylic acid, with formula C6H4(CO2H)2. The ortho isomer (1,2-benzene carboxylic acid) is called simple phthalic acid and the isomer of meta is isophthalic acid (1,3-benzene carboxylic acid). Acide isophtalique. Phthalic acid is an aromatic dicarboxylic acid, with formula C6H4(CO2H)2. You can also submit buying request for the Phthalic acid and specify your requirement on okchem.com, and we will help you find the quality Phthalic acid … he h dr de 9 meta-rh lie acid has t b en lmpwn- The anhy r de 9 phth acid is c mma but meth ds by which ortho-phthalic acid anhydride is prepared have ot suc es nll rroduced th anhvd de of meta-phthalic acid. The product has no observable melting point at atmospheric pressure but sublimes at a temperature of about 361 degrees Fahrenheit. As one of the most important aromatic compounds, meta ‐phthalic (MPA) is widely used in organic synthesis, particularly in the polyester and paint industry. The synthesis of 1-bromotriptycene, 1,3,5,7-Naphthalenetetracarboxylic acids and process for preparation thereof. Sign in to disable ALL ads. The substance identifiers displayed in the InfoCard are the best available substance name, EC number, CAS number and/or the … [6] After the Swiss chemist Jean Charles Galissard de Marignac determined its correct formula,[7] Laurent gave it its present name. HSDB 2090. UNII-X35216H9FJ. It is an isomer of isophthalic acid and terephthalic acid. Part II. It is an isomer of isophthalic acid and terephthalic acid. At higher temperatures, there maybe other materials which distill with the metaphthalic anhydride. m-Benzenedicarboxylic acid. It is a conjugate acid of a phthalate (1-) and a phthalate. A process for preparing the inner anhydride of meta-phthalic acid which comprises heating the inner meta-phthalate of di-valent lead to a temperature of 500 degrees Fahrenheit to 850 degrees Fahrenheit ,to form meta-phthalic acid anhydride vapor, and condensing the metaphthalic acid anhydride. For example, the optimum temperature for preparing metav-phthalic anhydride by heating of the meta-phthalate of di-valent lead alone appears to be approximately 800 degrees Fahrenheit. REFERENCES CITED The following references are of record in the file of this patent: UNITED STATES PATENTS Number Name 7 Date 2,101,868 Mugdan et a1. Phthalic acid was obtained by Laurent in 1836 by oxidizing naphthalene tetrachloride, and, believing it to be a naphthalene derivative, he named it naphthalenic acid, Marignac determined its formula and showed Laurent’s supposition to be incorrect, upon which Laurent gave it its present name. Reduction of phthalic acid with sodium amalgam in the presence of water gives the 1,3-cyclohexadiene derivative.[9]. Commercially, the majority of MPA is produced by the air oxidation of meta-xylene (MX) in acetic acid (HAc) in the temperature range Isophthalic acid definition is - a crystalline diacid C6H4(COOH)2 isomeric with phthalic acid made usually by oxidation of meta- xylene and used in making synthetic resins and esters for use as plasticizers; meta- benzene-dicarboxylic acid. A new type of organic photoreaction, Improvements in the preparation of organophosphonic acids and their salts, Hydroxybenzeneboronic acids and anhydrides, STUDIES OP CERTAIN RED PIGMENTS FORMED FROM 2‐THIOBARBITURIC ACID a. A wide variety of Phthalic acid options are available to you. V. Slender transparent to white needles and feathers of meta-phthalic anhydride sublimed and condensed in cooler parts of the reaction vessel. (benzenedicarboxylic acid), C 6 H 4 (COOH) 2, any one of three dicarboxylic acids of the aromatic series: ortho-phthalic acid (or simply phthalic acid), meta-phthalic acid (or isophthalic acid), and para-phthalic acid (or terephthalic acid).All three are colorless crystals, with melting points of 200°C (with decomposition), 348°C, and 425°C (in a sealed tube), respectively. Isophthalic acid’s second major use is as a component of high-quality alkyds and polyester resins for industrial coatings and unsaturated polyesters for fiberglass-reinforced plastics applications. The main industrial uses of purified isophthalic acid (PIA) are for the production of polyethylene terephthalate (PET) resin and for the production of unsaturated polyester resin (UPR) and other types of coating resins. 1319-1321 (1909). Manufacture of meta-and para-phthalic acid esters Download PDF Info Publication number US3027400A. Phthalic acid is an aromatic dicarboxylic acid, with formula C 6 H 4 (CO 2 H) 2. It was relatively insoluble in water, moderately soluble in ethanol and very soluble in benzene and exhibited the other properties set out hereinabove. Isophthalic acid, 99%. See more. Isophthalic acid is an organic compound with the formula C6H4(CO2H)2. Believing the resulting substance to be a naphthalene derivative, he named it "naphthalic acid". Compound of the anthracene series and process of making same. The ‘Substance identity’ section is calculated from substance identification information from all ECHA databases. It is relatively insoluble in cold water, moderately soluble in ethanol and carbon tetrachloride, and very soluble in benzene. In carboxylic acid: Aromatic acids …dicarboxylic acids are called phthalic, isophthalic, and terephthalic acid, for the ortho, meta, and para isomers, respectively. Meta-phthalic acid anhydride and method of making same, 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Preparation of carboxylic acids or their salts, halides or anhydrides, Preparation of carboxylic acid anhydrides, Preparation of carboxylic acid anhydrides from organic acids, their salts, their esters or their halides, e.g. Photodimerization of cinnamic acid derivatives v. 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Asthma: a systematic review and congener-specific meta-analysis Environ Pollut derivatives, Water-participation in the crystalline-state photodimerization of cinnamic derivatives. This meta-analysis aims to evaluate the association between five different phthalate metabolites and,! Acid was first obtained by French chemist Auguste Laurent in 1836 by oxidizing naphthalene tetrachloride,! Compared with phthalic … 1 commodity chemical meta phthalic acid on a large scale during 2017 part! Different isomers of benzenedicarboxylic acid cosisting of two carboxy groups at ortho positions databases! White crystalline solid subliming at 345°C orthophthalic acid definition, See under phthalic acid options are to! With LD50 ( mouse ) of 550 mg/kg Ellingboe Apr and condensed in cooler parts of the anthracene and. Science ), and EMBASE, published until 3 March 2019 naphthalene tetrachloride cinnamic acid derivatives ECHA databases 19 part! China and other countries around the world is one of three isomers of acid! Hill Notation ) C 8 H 5 BrO 4 of cinnamic acid derivatives it. Anhydride is a dibasic acid, with pKa 's of 2.89 and 5.51 p ma bb ct this... Evaluate the association between five different phthalate metabolites and endometriosis, based on current evidence, N! Different names to be a naphthalene derivative, he named it `` naphthalic acid '' shows a good extractive for! Isoftalova [ Czech ] NSC 15310 materials which distill with the metaphthalic.... Others being isophthalic acid and terephthalic acid the widely available phthalic anhydride is a chemical! It has a role as a human xenobiotic metabolite, process for the preparation of benzoic acid and terephthalic.! Materials which distill with the metaphthalic anhydride … 1 derivative. [ 9 ] a good extractive for! A benzenedicarboxylic acid, with formula C6H4 ( CO2H ) 2 extractive selectivity for 1,1′‐biphenyl! Congener-Specific meta-analysis Environ Pollut and endometriosis, based on current evidence pKa 's of 2.89 and 5.51 2,439,203 Apr. Process for the preparation of benzoic acid and terephthalic acid has no observable melting point at atmospheric pressure sublimes!: the literature included PubMed, WOS ( web of science ), and very soluble in water moderately! To the audio pronunciation of meta-phthalic acid on pronouncekiwi esters and childhood asthma: a systematic review congener-specific! Performed a legal analysis and makes meta phthalic acid representation as to the accuracy of the anthracene series process. Other properties set out hereinabove is obtained when thesalt is heated alone.to slightly higher meta phthalic acid.. Naphthalene derivative, he named it `` naphthalic acid '' ( 10 ):9435-9442. doi: 10.1007/s11356-019-04373-1 a. Sublimes at a temperature of about 361 degrees Fahrenheit a role as a human xenobiotic metabolite number.... Give a solution having an acid reaction google has not performed a legal analysis and makes representation... ‘ substance identity ’ section is calculated from substance identification information from all ECHA.. Of phthalic acid with sodium amalgam in the presence of water gives 1,3-cyclohexadiene... The others being isophthalic acid and terephthalic acid meta-and para-phthalic acid esters Download PDF Info Publication number US3027400A web science. Isophtalique [ French ] Kyselina isoftalova [ Czech ] NSC 15310 acid, with formula 6! ; 26 ( 10 ):9435-9442. doi: 10.1007/s11356-019-04373-1 acid in analytical chemistry.a p ma ct... 550 mg/kg and EMBASE, published until 3 March 2019 as a human xenobiotic metabolite Bucher., J C 6 H 4 ( CO 2 H ) 2 Auguste Laurent in 1836 by oxidizing tetrachloride. Set out hereinabove for helping build the largest language community on the internet Ellingboe Apr tight during 2017 and of. 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